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Duriel, the Lord of Pain
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Duriel is the twin of Andariel. I believe that they conspired together to assist Diablo in releasing Mephisto and Baal, though they had both supported the Lesser Evils in the past. The Lord of Pain was found guarding Baal's prison—the tomb of Tal Rasha—when he was slain by heroes.
Duriel, the Lord of Pain is lootable from Cain's Lost Satchel in Secret Altar, Stinging Winds, The Ruins, Road to Alcarnus, Flooded Causeway, Ruined Cistern, Dahlgur Oasis, The Forgotten Ruins, and Vault of the Assassin.